Article In: orcid, cienciavitae

Synthesis of transition-metal Lewis acid adducts of trans-[ReCl(CNR)(Ph2PCH2CH2PPh2 )2] (R = alkyl). A chemical and a quantum-chemical study of electrophilic β-addition to ligating isocyanide

Journal of Organometallic Chemistry

Fernanda, M.; Carvalho, N.N.; Tsipis, C.A. — 1989 — Elsevier

Key information

Authors:

Fernanda, M. (Maria Fernanda Do Nascimento Neves de Carvalho); Carvalho, N.N.; Pombeiro, A.J.L. (Armando José Latourrette de Oliveira Pombeiro); Bakalbassis, E.G.; Tsipis, C.A.

Published in

1989

Abstract

Treatment of trans-[ReCl(CNR)(dppe)2] (R = Me or But, dppe = Ph2PCH2CH2 PPh2) with CoCl2(THF)1.5, [ReOCl3(PPh3)2] or [WCl4L2] (L = PPh3 or PEtPh2) affords the dinuclear adducts [ReCl(CN(M)R)(dppe)2] (M = CoCl2(THF), ReOCl3(PPh3) or WCl4L, respectively) (formed via electrophilic β-addition of the electron-acceptor molecules to the isocyanide ligands), which undergo dissociation oxidation (for M = CoCl2(THF) or ReOCl3(PPh3)). These reactions are considered in the light of results of extended Hückel calculations.

Publication details

Authors in the community:

Publisher

Elsevier

Link to the publisher's version

https://www.sciencedirect.com/science/article/abs/pii/0022328X89852210

Title of the publication container

Journal of Organometallic Chemistry

First page or article number

C26

Last page

C30

Volume

371

Issue

1

DOI

10.1016/0022-328X(89)85221-0

Fields of Science and Technology (FOS)

chemical-sciences - Chemical sciences

Publication language (ISO code)

eng - English

Alternative identifier (URI)

http://www.scopus.com/inward/record.url?eid=2-s2.0-50849145888&partnerID=MN8TOARS

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