Article In: orcid

Diazenido, dinitrogen and triisocyanide complexes of rhenium(I) with phosphite or phosphonite co-ligands

Polyhedron

Carvalho, M. Fernanda N. N. ; Pombeiro, A.J.L. — 1989 — Elsevier

Key information

Authors:

Carvalho, M. Fernanda N. N. (Maria Fernanda Do Nascimento Neves de Carvalho); Pombeiro, A.J.L. (Armando José Latourrette de Oliveira Pombeiro)

Published in

1989

Abstract

Treatment of [ReCI2(NNCOPh)(PPh3)2] with P(OMe)3, PPh(OEt)2 or PPh(OMe)2, in benzene and in the presence of hot methanol, leads to the formation of [ReCl(N2)(PPh3)L3] [L = P(OMe)3 or PPh(OEt)2] or [ReCl(N2){PPh(OMe)2}4], whereas, without hot methanol, intermediate benzoyldiazenido species are obtained. The dinitrogen complexes react with isocyanides to afford [ReCl(CNR)3L2] [R = Me, L = PPh(OMe)2; R = C6H4Me-, L = P(OMe)3].

Publication details

Authors in the community:

Publisher

Elsevier

Link to the publisher's version

https://www.sciencedirect.com/science/article/abs/pii/S0277538700806403

Title of the publication container

Polyhedron

First page or article number

1778

Last page

1779

Volume

8

Issue

13-14

DOI

10.1016/S0277-5387(00)80640-3

Fields of Science and Technology (FOS)

chemical-sciences - Chemical sciences

Publication language (ISO code)

eng - English

Rights type:

Only metadata available