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Synthesis, Characterisation and Molecular Hyperpolarisabilities of Pseudo- Octahedral Hydrido(nitrile)iron(II) Complexes for Nonlinear Optics: X-ray Structure of [Fe(H)(dppe)2(4-NCC6H4NO2)][PF6]·CH2Cl2

Teixeira, António P. S.; Robalo, Maria Paula; Goovaerts, Etienne — 2006

Key information

Authors:

Teixeira, António P. S.; Robalo, Maria Paula (Maria Paula Alves Robalo); Garcia, Maria Helena; Piedade, M. Fátima Minas; Duarte, M. Teresa; Dias, Alberto Romão; Campo, Jochen; Wenseleers, Wim; Goovaerts, Etienne

Published in

2006

Abstract

A series of ionic pseudo-octahedral trans-hydrido(nitrile)- iron(II) complexes with the general formula [Fe(H)(dppe)2(4- NCR)][PF6] [dppe = 1,2-bis(diphenylphosphanyl)ethane; R = acceptor-substituted conjugated ligand] have been synthesised by chloride abstraction from the starting compound trans-[FeHCl(dppe)2] and fully characterised. First hyperpolarisabilities (ß) have been determined by hyper-

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Publication version

AO - Author's Original

Fields of Science and Technology (FOS)

chemical-sciences - Chemical sciences

Publication language (ISO code)

eng - English

Alternative identifier (URI)

http://hdl.handle.net/10174/5825

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