Dissertação de Mestrado

Life Cycle Assessment of bio-oil produced through lignocellulosic biomass liquefaction

Ana Sofia Lucas Silva Reis Augusto2022

Informações chave

Autores:

Ana Sofia Lucas Silva Reis Augusto (Ana Sofia Lucas Silva Reis Augusto)

Orientadores:

Ana Catarina Gouveia Braz (Ana Catarina Gouveia Braz); Maria Margarida Mateus

Publicado em

16/11/2022

Resumo

Over the past decade, global concerns about climate change have arisen, prompting interest in biomass-based goods, particularly, in the conversion of biomass into fuels. Thus, studies have been developed in biofuel produced through lignocellulosic biomass liquefaction. To assess the environmental impact of the production of this biofuel, a Life Cycle Assessment (LCA) has been conducted. Resorting to SimaPro software, the phases of transportation of feedstock, pre-treatment, and manufacturing process were considered. Additionally, the bio-oil's lower heating value (LHV) was calculated to know how much petcoke could be replaced by the bio-oil produced and introduced as environmental credits. A comparative environmental impact evaluation of hexane, heptane, cyclohexanol and user-defined 2-ethyl-hexanol as possible solvents used in the production of liquefied biomass, was performed to find a possible substitute for 2-ethyl hexanol in SimaPro. Additionally, tests were carried out on biomass sources (Eucalyptus and paper sludge) to study the influence of their composition. The data was provided by the company SECIL. The PEF and ReCiPe methodologies were used in calculating the global environmental impact. Comparing the fuels, it takes more amount of bio-oil to equal the LHV of petcoke, which is 21.06 and 15.7 Gj/ton for biomass from Eucalyptus and paper sludges, respectively. Through the analysed scenarios, the best eco-friendly case is the bio-oil from Eucalyptus with a mixture of the solvents 2-ethyl hexanol and glycerine in a proportion of 0.25:0.75, with a single environmental impact score of -1.35 mPt and 1.49 mPt for BATCH and continuous conditions, respectively when PEF was used.

Detalhes da publicação

Autores da comunidade :

Orientadores desta instituição:

Domínio Científico (FOS)

chemical-engineering - Engenharia Química

Idioma da publicação (código ISO)

por - Português

Acesso à publicação:

Embargo levantado

Data do fim do embargo:

29/09/2023

Nome da instituição

Instituto Superior Técnico